Skip to content
GitLab
Projects Groups Topics Snippets
  • /
  • Help
    • Help
    • Support
    • Community forum
    • Submit feedback
  • Sign in
  • GHOST GHOST
  • Project information
    • Project information
    • Activity
    • Labels
    • Members
  • Repository
    • Repository
    • Files
    • Commits
    • Branches
    • Tags
    • Contributor statistics
    • Graph
    • Compare revisions
  • Issues 24
    • Issues 24
    • List
    • Boards
    • Service Desk
    • Milestones
  • Merge requests 0
    • Merge requests 0
  • CI/CD
    • CI/CD
    • Pipelines
    • Jobs
    • Schedules
  • Deployments
    • Deployments
    • Environments
    • Releases
  • Monitor
    • Monitor
    • Incidents
  • Analytics
    • Analytics
    • Value stream
    • CI/CD
    • Repository
  • Wiki
    • Wiki
  • Snippets
    • Snippets
  • Activity
  • Graph
  • Create a new issue
  • Jobs
  • Commits
  • Issue Boards
Collapse sidebar
  • Atmospheric Composition
  • GHOSTGHOST
  • Wiki
  • Measurement Procedure Standardisations

Measurement Procedure Standardisations · Changes

Page history
Update Measurement Procedure Standardisations authored Jul 18, 2019 by dbowdalo's avatar dbowdalo
Show whitespace changes
Inline Side-by-side
Measurement-Procedure-Standardisations.md
View page @ 2c9da6d5
...@@ -64,7 +64,7 @@ Now the ...@@ -64,7 +64,7 @@ Now the
| Method | Principle | Known Issues | Measured Compounds | | Method | Principle | Known Issues | Measured Compounds |
| ------ | ----------| ------------ | ------------------ | | ------ | ----------| ------------ | ------------------ |
| Ultraviolet Photometry | Operates on the principle that a specific species efficiently absorbs light at a known wavelength in the UV range. This is the case for ozone, at 253.65nm. The degree to which the UV light is absorbed by a specific species is directly related to the species concentration as described by the Beer-Lambert Law (I/Io = e−KLC; K = molecular absorption coefficient at STP (308 cm-1 atm-1 for O3), L = optical path length of cell, C = species concentration , I = light intensity of sample gas, Io = light intensity of sample without measured species (reference gas) ) | Gaseous hydrocarbons with strong absorption at 254 nm, such as aromatic hydrocarbons (i.e., benzene and substituted benzene rings)| O3 | | Ultraviolet Photometry | Operates on the principle that a specific species efficiently absorbs light at a known wavelength in the UV range. This is the case for ozone, at 253.65nm. The degree to which the UV light is absorbed by a specific species is directly related to the species concentration as described by the Beer-Lambert Law (I/Io = e<sup>−KLC</sup>; K = molecular absorption coefficient at STP (308 cm<sup>-1</sup> atm-1 for O3), L = optical path length of cell, C = species concentration , I = light intensity of sample gas, Io = light intensity of sample without measured species (reference gas) ) | Gaseous hydrocarbons with strong absorption at 254 nm, such as aromatic hydrocarbons (i.e., benzene and substituted benzene rings)| O3 |
| Visible Photometry | Operates on the principle that a specific species efficiently absorbs light at a known wavelength in the visible range. This is the case for NO2, at 405nm. The degree to which the visible light is absorbed by a specific species is directly related to the species concentration as described by the Beer-Lambert Law (C = 1/Lσ * ln(Io/I) ; σ = absorption cross section (6.06×10-19 cm2 molec-1 for NO2 at 405nm), L = optical path length of cell, C = species concentration , I = light intensity of sample gas, Io = light intensity of sample without measured species (reference gas) ). | Water vapour, small particles (< 5 um) | | | Visible Photometry | Operates on the principle that a specific species efficiently absorbs light at a known wavelength in the visible range. This is the case for NO2, at 405nm. The degree to which the visible light is absorbed by a specific species is directly related to the species concentration as described by the Beer-Lambert Law (C = 1/Lσ * ln(Io/I) ; σ = absorption cross section (6.06×10-19 cm2 molec-1 for NO2 at 405nm), L = optical path length of cell, C = species concentration , I = light intensity of sample gas, Io = light intensity of sample without measured species (reference gas) ). | Water vapour, small particles (< 5 um) | |
| Ethylene Chemiluminescence | Chemiluminescence is the emission of light (luminescence), as the result of a chemical reaction. Chemiluminescence occurs as a result of the reaction of ozone with ethylene, leading to an excited molecule. The return to a fundamental electronic state of the excited molecules is made by luminous radiation in a specific spectrum, which can be measured. The concentration of sample ozone is directly proportional to the intensity of light emitted. The broadband emission is detected using a photomultiplier tube (at 440 nm for ethylene + ozone). | Water vapour | | | Ethylene Chemiluminescence | Chemiluminescence is the emission of light (luminescence), as the result of a chemical reaction. Chemiluminescence occurs as a result of the reaction of ozone with ethylene, leading to an excited molecule. The return to a fundamental electronic state of the excited molecules is made by luminous radiation in a specific spectrum, which can be measured. The concentration of sample ozone is directly proportional to the intensity of light emitted. The broadband emission is detected using a photomultiplier tube (at 440 nm for ethylene + ozone). | Water vapour | |
| Eosin-Y Chemiluminescence | Chemiluminescence is the emission of light (luminescence), as the result of a chemical reaction. Chemiluminescence occurs as a result of the reaction of ozone with eosin-Y, leading to an excited molecule. The return to a fundamental electronic state of the excited molecules is made by luminous radiation in a specific spectrum, which can be measured. The concentration of sample ozone is directly proportional to the intensity of light emitted. The broadband emission is detected using a photomultiplier tube (at ~560 nm for eosin-Y + ozone). | Water vapour | | | Eosin-Y Chemiluminescence | Chemiluminescence is the emission of light (luminescence), as the result of a chemical reaction. Chemiluminescence occurs as a result of the reaction of ozone with eosin-Y, leading to an excited molecule. The return to a fundamental electronic state of the excited molecules is made by luminous radiation in a specific spectrum, which can be measured. The concentration of sample ozone is directly proportional to the intensity of light emitted. The broadband emission is detected using a photomultiplier tube (at ~560 nm for eosin-Y + ozone). | Water vapour | |
......
Clone repository
  • EBAS Network Processing
  • Home
  • Measurement Procedure Standardisations